August 4, 2021 - Free Activators

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Selective, radical-free activation of benzylic C–H bonds in methylarenes†

Author affiliations

* Corresponding authors

a Department of Chemistry, University of Liverpool, Crown Street, Liverpool, UK
E-mail:[email protected]

b Department of Chemistry, Lancaster University, Bailrigg, Lancaster, UK

Abstract

We report rare examples of exclusive benzylic C–H oxidative addition in industrially important methylarenes using simple η4-arene iridium complexes. Mechanistic studies showed that coordinatively unsaturated η2-arene intermediates are responsible for the selective activation of benzylic, not aromatic C–H bonds and formation of stable benzyl complexes after trapping with a phosphine ligand.

Graphical abstract: Selective, radical-free activation of benzylic C–H bonds in methylarenes

This article is Open Access

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Supplementary files

Article information

DOI
https://doi.org/10.1039/D1CC03445F

Article type
Communication

Submitted
28 Jun 2021

Accepted
13 Jul 2021

First published
13 Jul 2021

This article is Open Access
Creative Commons BY license

Chem. Commun., 2021,57, 7894-7897

Selective, radical-free activation of benzylic C–H bonds in methylarenes

A. P. Y. Chan, M. Jakoobi, C. Wang, Y. Tian, N. Halcovitch, R. Boulatov and A. G. Sergeev, Chem. Commun., 2021, 57, 7894 DOI: 10.1039/D1CC03445F

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Источник: https://pubs.rsc.org/en/Content/ArticleLanding/2021/CC/D1CC03445F

Downtown Sounds

Downtown Sounds

Downtown Sounds started as a small gathering hosted in an alley, turning the underutilized space into something extraordinary. And extraordinary it became. With each year the event grew, now taking up two entire city blocks on Bay and Prospect Streets. Downtown Sounds draws bands from across the country and folks from Whatcom County and beyond to share in their love of music. After 17 years of this beloved, award-winning, urban music festival, it is firmly cemented as Downtown Bellingham's hottest summer attraction.

2021 Series Lineup and Schedule:

August 4:Nite Wave with Analog Brass
August 11: Eldridge Gravy & the Court Supreme with Mind’s Eye
August 18:High Step Society with Stephanie Anne Johnson & The Hidogs
August 25: The Dusty 45s with Nuages


Beer garden opens at 5:30pm. Music from 6:00-9:00pm. Back on Bay & Prospect Streets.


Community Health & Safety

After June 30, 2021 physical distancing and capacity limitation restrictions were lifted for outdoor events. However, due to growing concern regarding the Delta variant, we have a few guidelines for Downtown Sounds concerts.

Guidelines:

  • Please stay home if you are sick, or if you’ve been in contact with someone who is sick.

  • Face coverings are required for any concert attendees who are unvaccinated, and all attendees are encouraged to bring a mask.

  • Whatcom County Health Department recommends individuals wear a mask or face covering during crowded outdoor events, like Downtown Sounds

Ultimately, getting vaccinated and wearing a mask is the best way to help keep our community healthy. Please be considerate of others while enjoying Downtown Sounds, and thank you for continuing to keep each other safe!

Holly Street closure:

To allow for more space among concert goers, we’ll be closing Holly Street to through traffic on Wednesdays in August so that we can all enjoy the music with a little more space to spread out.

Downtown INSIDER perks

Downtown INSIDERS skip the beer garden line at every concert, all summer long. This year, new INSIDERS who sign up at the $10+ level will enjoy their first drink token included with registration, which can be used for a glass of beer, wine or cider!

Источник: https://www.downtownbellingham.com/downtown-sounds

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Hazard Community and Technical College Logo

Welcome New Students

Welcome and congratulations on your acceptance to Hazard Community and Technical College. We are thrilled that you will be joining our family!

As a new student at HCTC, you are bound to have questions. New Student Orientation is designed around you, helping to uncover the answers to the questions you have, and providing you information about campus resources, programs and services. By the time you complete orientation, you'll be on your way to becoming a successful HCTC student.

You will learn a lot about HCTC at New Student Orientation. The program is an opportunity for you to learn how to navigate your HCTC journey on the right path. At New Student Orientation August 4 will find out more about:

  • Your schedule of classes
  • Financial aid and scholarships
  • Books
  • Tutoring
  • Clubs and Organizations
  • Student Account Activation
  • And many other campus resources!

Setting Up Your Student Account

At the KCTCS User Account Center you will be able to:  

  • Setup your User Profile: Have your personal (or home) email address or mobile phone number ready.
  • Update your User Profile: Update your password and information needed to verify your identity when you need 2021 - Free Activators to reset your password.
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The KCTCS User Account Center stores your information securely and provides access to your information online, 24/7.  August 4

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  1. Visit https://students.kctcs.edu
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  3. Enter your USERID using all capital letters (e.g., JSMITH0004).
  4. Enter your Password.
  5. Select the “Sign In” button.

All HCTC degree-seeking students must attend the New Student Orientation either in person or online.

ONLINE ORIENTATION

Источник: https://hazard.kctcs.edu/admissions/orientation/index.aspx

4 Replies to “August 4, 2021 - Free Activators”

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